Team:Oxford/modellingA

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<h1></h1>
 
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<h1>[DCM] calibration for solution-vapour equilibration</h1>
 
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<p>Testing the tolerance of E-coli and Pseudomonas strains to various concentrations of DCM (0mM, 5mM, 10mM, 20mM), the 15 mL falcon tube-contained system is modeled as a binary solution/ideal gas, based on literature solubility data, confirming negligible [DCM] deviation:</p>
 
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<img src="http://latex.codecogs.com/gif.latex?k(T)=k^\Theta&space;e^{\frac{\mathrm{d}&space;lnk}{\mathrm{d}&space;1/T}(\frac{1}{T}-\frac{1}{298.15K})}" title="k(T)=k^\Theta e^{\frac{\mathrm{d} lnk}{\mathrm{d} 1/T}(\frac{1}{T}-\frac{1}{298.15K})}" />
 
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<p class="p1"><br></p>
 
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<table cellspacing="0" cellpadding="0" class="t1">
 
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  <tbody>
 
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    <tr>
 
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      <td valign="top" class="td1">
 
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        <p class="p1"><br></p>
 
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      </td>
 
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      <td valign="top" class="td2">
 
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        <p class="p2"><span class="s1">p(DCM) /kPa</span></p>
 
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      </td>
 
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      <td valign="top" class="td3">
 
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        <p class="p2"><span class="s1">n</span><span class="s2"><sub>(g)</sub></span><span class="s1"> /mol</span></p>
 
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      </td>
 
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      <td valign="top" class="td4">
 
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        <p class="p2"><span class="s1">V(DCM)</span><span class="s2"><sub> </sub></span><span class="s1">added /ml</span></p>
 
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      </td>
 
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      <td valign="top" class="td5">
 
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        <p class="p2"><span class="s1">n(DCM)</span><span class="s2"><sub>(l)</sub></span><span class="s1"> unadjusted /mol</span></p>
 
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      </td>
 
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      <td valign="top" class="td1">
 
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        <p class="p2"><span class="s1">[DCM] unadjusted /M</span></p>
 
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      </td>
 
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      <td valign="top" class="td6">
 
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        <p class="p2"><span class="s1">n(DCM)</span><span class="s2"><sub>(l)</sub></span><span class="s1"> adjusted /mol</span></p>
 
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      </td>
 
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      <td valign="top" class="td7">
 
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        <p class="p2"><span class="s1">[DCM] adjusted /M</span></p>
 
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      </td>
 
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      <td valign="top" class="td8">
 
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        <p class="p2"><span class="s1">[DCM] % deviation</span></p>
 
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      </td>
 
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    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td9">
 
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        <p class="p2"><span class="s1"><b>(30°C, 5mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td10">
 
-
        <p class="p3"><span class="s1">1.56E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td11">
 
-
        <p class="p3"><span class="s1">3.94E-12</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td12">
 
-
        <p class="p3"><span class="s1">6.4E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td13">
 
-
        <p class="p3"><span class="s1">1.0E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td9">
 
-
        <p class="p3"><span class="s1">2.0E-02</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td14">
 
-
        <p class="p3"><span class="s1">1.0E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td15">
 
-
        <p class="p3"><span class="s1"><b>2.0E-02</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td16">
 
-
        <p class="p3"><span class="s1">3.9E-06</span></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p2"><span class="s1"><b>(30°C, 10mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td18">
 
-
        <p class="p3"><span class="s1">3.12E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td19">
 
-
        <p class="p3"><span class="s1">7.88E-12</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td20">
 
-
        <p class="p3"><span class="s1">3.2E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td21">
 
-
        <p class="p3"><span class="s1">5.0E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p3"><span class="s1">1.0E-02</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td22">
 
-
        <p class="p3"><span class="s1">5.0E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td23">
 
-
        <p class="p3"><span class="s1"><b>1.0E-02</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td24">
 
-
        <p class="p3"><span class="s1">1.6E-05</span></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p2"><span class="s1"><b>(30°C, 20mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td18">
 
-
        <p class="p3"><span class="s1">6.24E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td19">
 
-
        <p class="p3"><span class="s1">1.58E-11</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td20">
 
-
        <p class="p3"><span class="s1">1.6E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td21">
 
-
        <p class="p3"><span class="s1">2.5E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p3"><span class="s1">5.0E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td22">
 
-
        <p class="p3"><span class="s1">2.5E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td23">
 
-
        <p class="p3"><span class="s1"><b>5.0E-03</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td24">
 
-
        <p class="p3"><span class="s1">6.3E-05</span></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td9">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td10">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td11">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td25">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td13">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td9">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td14">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td26">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
      <td valign="top" class="td16">
 
-
        <p class="p1"><br></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p2"><span class="s1"><b>(37°C, 5mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td18">
 
-
        <p class="p3"><span class="s1">1.56E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td19">
 
-
        <p class="p3"><span class="s1">3.94E-12</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td20">
 
-
        <p class="p3"><span class="s1">6.4E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td21">
 
-
        <p class="p3"><span class="s1">1.0E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p3"><span class="s1">2.0E-02</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td22">
 
-
        <p class="p3"><span class="s1">1.0E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td23">
 
-
        <p class="p3"><span class="s1"><b>2.0E-02</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td24">
 
-
        <p class="p3"><span class="s1">3.9E-06</span></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p2"><span class="s1"><b>(37°C, 10mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td18">
 
-
        <p class="p3"><span class="s1">3.12E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td19">
 
-
        <p class="p3"><span class="s1">7.88E-12</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td20">
 
-
        <p class="p3"><span class="s1">3.2E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td21">
 
-
        <p class="p3"><span class="s1">5.0E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td17">
 
-
        <p class="p3"><span class="s1">1.0E-02</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td22">
 
-
        <p class="p3"><span class="s1">5.0E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td23">
 
-
        <p class="p3"><span class="s1"><b>1.0E-02</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td24">
 
-
        <p class="p3"><span class="s1">1.6E-05</span></p>
 
-
      </td>
 
-
    </tr>
 
-
    <tr>
 
-
      <td valign="top" class="td9">
 
-
        <p class="p2"><span class="s1"><b>(37°C, 20mM)</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td10">
 
-
        <p class="p3"><span class="s1">6.24E-04</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td11">
 
-
        <p class="p3"><span class="s1">1.58E-11</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td12">
 
-
        <p class="p3"><span class="s1">1.6E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td13">
 
-
        <p class="p3"><span class="s1">2.5E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td9">
 
-
        <p class="p3"><span class="s1">5.0E-03</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td14">
 
-
        <p class="p3"><span class="s1">2.5E-05</span></p>
 
-
      </td>
 
-
      <td valign="top" class="td15">
 
-
        <p class="p3"><span class="s1"><b>5.0E-03</b></span></p>
 
-
      </td>
 
-
      <td valign="top" class="td16">
 
-
        <p class="p3"><span class="s1">6.3E-05</span></p>
 
-
      </td>
 
-
    </tr>
 
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  </tbody>
 
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</table>
 
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<p class="p1"><br></p>
 
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</body>
 
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Latest revision as of 01:02, 18 October 2014

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